1-MESITYL-2,2,2-TRIFLUOROETHANOL, AN OUTSTANDING NEW CHIRAL CONTROLLER FOR CATALYZED DIELS-ALDER REACTIONS

被引：16

作者：

COREY, EJ

CHENG, XM

CIMPRICH, KA

机构：

[1] Department of Chemistry, Harvard University, Cambridge

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 47期

关键词：

D O I：

10.1016/0040-4039(91)80420-B

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The R2AlCl-catalyzed Diels-Alder reactions of cyclopentadiene with the (R)-1-mesityl-2,2,2-trifluoroethyl esters of acrylic and fumaric acid proceed with > 97:3 diastereoselectivity.

引用

页码：6839 / 6842

页数：4

共 11 条

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[2] 1-MESITYL-2,2,2-TRIFLUOROETHANOL, AN OUTSTANDING NEW CHIRAL CONTROLLER FOR CATALYZED DIELS-ALDER REACTIONS
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[6] CHIRAL SYNTHESIS OF ASYMMETRICALLY TETRA-C-SUBSTITUTED CYCLOPENTANE DERIVATIVES BY DIELS-ALDER ADDITION OF CYCLOPENTADIENE TO UNSATURATED ACYCLIC-SUGAR DERIVATIVES
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[7] 2-NORBORNANEDIAZONIUM IONS REVISITED
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[9] IMPROVED METHOD FOR THE PREPARATION OF ENANTIOMERICALLY PURE SULFINATE ESTERS
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