SYNTHESIS OF ACYLSILANES VIA SILASTANNATION OF ALKYNES BY A PALLADIUM ISOCYANIDE CATALYST

被引：63

作者：

MURAKAMI, M ^{[1
]}

AMII, H ^{[1
]}

TAKIZAWA, N ^{[1
]}

ITO, Y ^{[1
]}

机构：

[1] KYOTO UNIV,FAC ENGN,DEPT SYNTHET CHEM,KYOTO 60601,JAPAN

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 10期

关键词：

D O I：

10.1021/om00034a072

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Silastannation of 1-alkoxyalkynes was carried out at room temperature by use of a palladium acetate/tert-alkyl isocyanide catalyst, to produce 1-alkoxy-1-silyl-2-stannylalkenes. Palladium-mediated coupling of the organotin moieties with organic halides followed by acid-catalyzed hydrolysis provided a variety of acylsilanes.

引用

页码：4223 / 4227

页数：5

共 27 条

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