REACTIONS OF ALKYL MALONATES WITH MOLYBDENUM AND TUNGSTEN COMPLEXES - SYNTHESES AND STRUCTURE OF HYDRIDO-MALONATO COMPLEXES

被引：8

作者：

MINATO, M

KURISHIMA, S

NAGAI, K

YAMASAKI, M

ITO, T

机构：

[1] YOKOHAMA NATL UNIV, FAC ENGN, DEPT CHEM MAT, HODOGAYA KU, YOKOHAMA, KANAGAWA 240, JAPAN

[2] RIGAKU CORP, AKISHIMA, TOKYO 196, JAPAN

来源：

CHEMISTRY LETTERS | 1994年 / 12期

关键词：

D O I：

10.1246/cl.1994.2339

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molybdenum and tungsten hydrido-malonato complexes have been prepared by the photochemical or thermal reactions of [MoH4(dppe)(2)] or trans-[W(N-2)(2)(dppe)(2)] with an excess of alkyl malonates. The structure of the complex is reported, and a possible mechanism is proposed for the reaction.

引用

收藏

页码：2339 / 2342

页数：4

相关论文

共 13 条

[1]

COTTON FA, 1988, ADV INORG CHEM RAD, P477

[2]

GEOFFROY GL, 1979, ORGANOMETALLIC PHOTO, P278

[3] STUDIES ON ENOL TITRATION .2. ENOL CONTENTS OF SOME KETONES AND ESTERS IN THE PRESENCE OF METHANOL [J].

GERO, A .

JOURNAL OF ORGANIC CHEMISTRY, 1954, 19 (12) :1960-1970

[4] SELECTIVE ACTIVATION OF OLEFINIC C-H BONDS - REACTION OF A HYDRIDOMOLYBDENUM COMPLEX WITH METHACRYLIC ESTERS TO FORM HYDRIDO ALKENYL COMPLEXES [J].

ITO, T ;

TOSAKA, H ;

YOSHIDA, S ;

MITA, K ;

YAMAMOTO, A .

ORGANOMETALLICS, 1986, 5 (04) :735-739

[5] SELECTIVE C-O BOND-CLEAVAGE OF ALLYLIC ESTERS USING [MOH4(PH2PCH2CH2PPH2)2] UNDER LIGHT IRRADIATION TO GIVE HYDRIDOCARBOXYLATOMOLYBDENUM(II) COMPLEXES [J].

ITO, T ;

MATSUBARA, T ;

YAMASHITA, Y .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (08) :2407-2412

[6] OXIDATIVE ADDITION OF N-SUBSTITUTED AMIDES TO MOLYBDENUM(II) INVOLVING N-H BOND-CLEAVAGE TO GIVE (ETA-2-N-ACYLAMIDO-N,O)HYDRIDOMOLYBDENUM(II) COMPLEXES - X-RAY MOLECULAR-STRUCTURE OF THE 7-COORDINATE COMPLEX [MOH(N(COCH3)CH3)((C6H5)2PCH2CH2P(C6H5)2)2] [J].

ITO, T ;

KURISHIMA, S ;

TANAKA, M ;

OSAKADA, K .

ORGANOMETALLICS, 1992, 11 (07) :2333-2335

[7] PREPARATION AND CHARACTERIZATION OF (1-2-ETA-ETHYLENE)BIS[1,2-BIS[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]MOLYBDENUM(0) AND BIS[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]HYDRIDO(PENTANE-2,4-DIONATO)MOLYBDENUM(II) [J].

ITO, T ;

KOKUBO, T ;

YAMAMOTO, T ;

YAMAMOTO, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (16) :1783-1787

[8]

ITO T, 1990, ORGANOMETALLICS, P1645

[9] STRUCTURAL CHARACTERIZATION OF THE TRANSITION-METAL IMIDO COMPLEX COORDINATED IN A BIDENTATE FASHION - PREPARATION AND THE MOLECULAR-STRUCTURE OF 7-COORDINATE HYDRIDO(SUCCINIMIDO-N,O)-BIS[1,2-BIS(DIPEHNYLPHOSPHINO)ETHANE]MOLYBDENUM(II) [J].

KURISHIMA, S ;

ITO, T .

CHEMISTRY LETTERS, 1990, (08) :1299-1302

[10]

LIKAO J, 1993, TRANSIT METAL CHEM, V18, P265