A REGIOCHEMICAL CONTROL IN THE PI-ALLYLPALLADIUM SUBSTITUTION - PREPARATION OF OPTICALLY-ACTIVE GAMMA-SILYLALLYLAMINES

被引：32

作者：

INAMI, H ^{[1
]}

ITO, T ^{[1
]}

URABE, H ^{[1
]}

SATO, F ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,DEPT BIOMOLEC ENGN,4259 NAGATSUTA CHO,MIDORI KU,YOKOHAMA,KANAGAWA 227,JAPAN

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 37期

关键词：

D O I：

10.1016/S0040-4039(00)73814-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Optically active gamma-trimethysilylallylamine derivatives were prepared from gamma-trimethylsilylallyl alcohols via i. derivatization to carbonates and ii. palladium-catalyzed, regioselective allylic substitution by nitrogen nucleophiles without loss of the enantiomeric purities of the starting alcohols.

引用

页码：5919 / 5922

页数：4

共 35 条

[31] ALPHA-ELIMINATION OF ALPHA-ACETOXYSILANES INDUCED BY PALLADIUM - EVIDENCE FOR THE INTERMEDIACY OF A VINYLCARBENE PALLADIUM COMPLEX
TROST, BM
SELF, CR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (18) : 5942 - 5944
[32] PALLADIUM-CATALYZED REGIOSELECTIVE REACTIONS OF SILYL-SUBSTITUTED ALLYLIC CARBONATES AND VINYL EPOXIDE
TSUJI, J
YUHARA, M
MINATO, M
YAMADA, H
SATO, F
KOBAYASHI, Y
[J]. TETRAHEDRON LETTERS, 1988, 29 (03) : 343 - 346
[33] Tsuji J., 1980, ORGANIC SYNTHESIS PA
[34] (ETA-6-ARENE) TRICARBONYL CHROMIUM COMPLEXES IN ORGANIC-SYNTHESIS 1,5-REMOTE DIASTEREOSELECTION
UEMURA, M
MINAMI, T
HAYASHI, Y
[J]. TETRAHEDRON LETTERS, 1988, 29 (48) : 6271 - 6274
[35] STUDIES ON THE ENANTIOSELECTIVITY IN BU4N[FE(CO)3NO]-CATALYZED NUCLEOPHILIC-SUBSTITUTION OF OPTICALLY-ACTIVE ALLYLIC CARBONATES WITH MALONATE
ZHOU, B
XU, YY
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (18) : 4419 - 4421

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