GEOGRAPHICAL-DISTRIBUTION OF TAMARISCOL, A MOSSY ODOROUS SESQUITERPENE ALCOHOL, IN THE LIVERWORT FRULLANIA-TAMARISCI AND RELATED SPECIES

被引:18
作者
ASAKAWA, Y [1 ]
SONO, M [1 ]
WAKAMATSU, M [1 ]
KONDO, K [1 ]
HATTORI, S [1 ]
MIZUTANI, M [1 ]
机构
[1] HATTORI BOT LAB,MIYAZAKI 88925,JAPAN
关键词
FRULLANIA-TAMARISCI; F-CALIFORNICA; F-NEPALENSIS; JUNGERMANNIALES; HEPATICAE; TAMARISCOL; SESQUITERPENE ALCOHOL; SESQUITERPENE LACTONES; MOSSY ODOR; CHEMOSYSTEMATICS;
D O I
10.1016/0031-9422(91)83633-V
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
There are two chemotypes (Type-T and Type-O) of the liverwort Frullania tamarisci subsp. obscura. The former type produces tamariscol, possessing the intense mossy odour, and 5-alpha,7-beta(H)-eudesm-4-alpha,6-alpha-diol as the major components and the latter type lacks the above two sesquiterpenoids while eudesmanolides are predominant. Type-T is chemically similar to F. tamarisci subsp. asagrayana and F. tamarisci subsp. tamarisci, although the sesquiterpene lactones present are different. Frullania tamarisci subsp. nisquallensis is chemically close to F. tamarisci subsp. asagrayana and F. tamarisci subsp. tamarisci, except for the absence of tamariscol. F. nepalensis produces tamariscol as the minor component, but the sesquiterpene lactone class is different from that of the F. tamarisci complex containing tamariscol.
引用
收藏
页码:2295 / 2300
页数:6
相关论文
共 17 条
[1]  
ASAKAWA Y, 1976, Miscellanea Bryologica et Lichenologica, V7, P99
[2]   CHEMOSYSTEMATICS OF BRYOPHYTES .22. BIBENZYL DERIVATIVES FROM THE AUSTRALIAN LIVERWORT FRULLANIA-FALCILOBA [J].
ASAKAWA, Y ;
TAKIKAWA, K ;
TORI, M .
PHYTOCHEMISTRY, 1987, 26 (04) :1023-1025
[3]   CHEMOSYSTEMATICS OF BRYOPHYTES .10. TERPENOIDS AND BIBENZYLS OF 25 LIVERWORT FRULLANIA SPECIES [J].
ASAKAWA, Y ;
MATSUDA, R ;
TOYOTA, M ;
HATTORI, S ;
OURISSON, G .
PHYTOCHEMISTRY, 1981, 20 (09) :2187-2194
[4]   BIBENZYL DERIVATIVES FROM FRULLANIA SPECIES [J].
ASAKAWA, Y ;
MATSUDA, R ;
CHEMINAT, A .
PHYTOCHEMISTRY, 1987, 26 (04) :1117-1122
[5]  
Asakawa Y., 1990, Bryophyte development: physiology and biochemistry., P259
[6]  
ASAKAWA Y, 1983, PHYTOCHEMISTRY, V22, P961, DOI 10.1016/0031-9422(83)85030-4
[7]  
ASAKAWA Y, 1982, PROG CH ORG NAT PROD, V42, P1
[8]  
ASAKAWA Y, 1987, STUDIES CRYPTOGAMS S, P111
[9]   THE STRUCTURE OF TAMARISCOL, A NEW PACIFIGORGIANE SESQUITERPENOID ALCOHOL FROM THE LIVERWORT FRULLANIA-TAMARISCI [J].
CONNOLLY, JD ;
HARRISON, LJ ;
RYCROFT, DS .
TETRAHEDRON LETTERS, 1984, 25 (13) :1401-1402
[10]   CHEMOSYSTEMATICS OF BRYOPHYTES .44. BIS(BIBENZYL) ETHERS FROM PELLIA-ENDIVIIFOLIA [J].
HASHIMOTO, T ;
SUZUKI, H ;
TORI, M ;
ASAKAWA, Y .
PHYTOCHEMISTRY, 1991, 30 (05) :1523-1530