THE REACTIONS OF [FEH(H2)(ME2PCH2CH2PME2)2][BPH4] WITH ALLENES AND ACETYLENES, AND THE REDUCTION OF CYCLOPROPENE BY MOLYBDENUM NITROGENASES

被引：55

作者：

HILLS, A ^{[1
]}

HUGHES, DL ^{[1
]}

JIMENEZTENORIO, M ^{[1
]}

LEIGH, GJ ^{[1
]}

MCGEARY, CA ^{[1
]}

ROWLEY, AT ^{[1
]}

BRAVO, M ^{[1
]}

MCKENNA, CE ^{[1
]}

MCKENNA, MC ^{[1
]}

机构：

[1] UNIV SO CALIF, DEPT CHEM, LOS ANGELES, CA 90089 USA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 07期

关键词：

D O I：

10.1039/c39910000522

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reduction of cyclopropenes by metal hydrides shows significant parallels with their reduction by Klebsiella pneumoniae nitrogenase; intermediates isolated from the reduction of the isomeric allenes and acetylenes by [FeH(H2)(Me2PCH2CH2PMe2)2][BPh4] show novel features of much wider implication.

引用

页码：522 / 524

页数：3

共 16 条

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