A NOVEL MIXED-VALENCE TETRANUCLEAR V(II)/V(III) COMPLEX ISOLATED FROM 3,5-DI-TERT-BUTYLCATECHOL VANADIUM(II) SODIUM METHOXIDE SYSTEM FOR DINITROGEN REDUCTION

被引：27

作者：

LUNEVA, NP

MIRONOVA, SA

SHILOV, AE

ANTIPIN, MY

STRUCHKOV, YT

机构：

[1] Institute of Chemical Physics, Russian Academy of Sciences, Chernogolovka

[2] Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 08期

关键词：

D O I：

10.1002/anie.199311781

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Vanadium centers octahedrally surrounded by oxygen atoms are found in the crystals of the title compound 1. This mixed-valent complex can be isolated from the N2-reducing system dbcat/VCl2/NaOCH3 in methanol after the catalytic activity has ceased. The structure of 1 supports the conjecture that multinuclear complexes participate in N2-reducing systems in protic media. dbcat = 3,5-di-tert-butylcatecliol.

引用

页码：1178 / 1179

页数：2

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