FORMAL HYDROALLYLATION OF CARBON-CARBON TRIPLE BONDS VIA TANTALUM-ALKYNE COMPLEXES - STEREOSELECTIVE PREPARATION OF 1,4-DIENES

被引：24

作者：

TAKAI, K ^{[1
]}

YAMADA, M ^{[1
]}

ODAKA, H ^{[1
]}

UTIMOTO, K ^{[1
]}

FUJII, T ^{[1
]}

FURUKAWA, I ^{[1
]}

机构：

[1] DOSHISHA UNIV, FAC ENGN, DEPT MOLEC SCI & TECHNOL, TANABE, KYOTO 61003, JAPAN

来源：

CHEMISTRY LETTERS | 1995年 / 04期

关键词：

D O I：

10.1246/cl.1995.315

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of tantalum-alkyne complexes with lithium salts of allylic alcohols in DME-benzene-THF (1:1:1) at 25 degrees C for several hours gives 1,4-dienes stereoselectively in good to excellent yields.

引用

页码：315 / 316

页数：2

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