NATURAL-PRODUCTS SYNTHESIS BY RETRO-DIELS-ALDER REACTION .7. HIGHLY ENANTIOSELECTIVE SYNTHESIS OF (+) AND (-)ENDO-TRICYCLO [5.2.1.02,6]DECA-4,8-DIEN-3-ONE AND (-)-4-T-BUTYLDIMETHYLSILYLOXY-CYCLOPENTENONE BY ENZYME-CATALYZED ACETYLATION

被引：29

作者：

LIU, ZY ^{[1
]}

HE, L ^{[1
]}

ZHENG, H ^{[1
]}

机构：

[1] W CHINA UNIV MED SCI,COLL PHARM,CHENGDU 610041,PEOPLES R CHINA

来源：

TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 11期

关键词：

D O I：

10.1016/S0957-4166(00)80081-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Asymmetric syntheses of enantiomerically pure (+)- and (-)-5 and (-)-8 are described with enzyme-catalyzed acetylation of the meso-diol 2 as the key step.

引用

页码：2277 / 2278

页数：2

共 14 条

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[2] OPTICAL RESOLUTION OF 3A,4,7,7A-TETRAHYDRO-4,7-METHANO-1H-INDENE DERIVATIVES
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[3] A STEREOSPECIFIC FORMAL SYNTHESIS OF CLAVULONES FROM TRICYCLO[5.2.1.0(2,6)]DECADIENONE EPOXIDES
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[J]. TETRAHEDRON LETTERS, 1991, 32 (26) : 3131 - 3132
[4] ENZYMATIC OPTICAL RESOLUTION AND ABSOLUTE-CONFIGURATION OF TRICYCLO[5.2.1.02,6]DECADIENONES
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[5] LIU Z, IN PRESS
[6] LIU ZY, 1993, TETRAHEDRON LETT, V34, P349
[7] LIU ZY, 1991, SYNLETT, P191
[8] A CONCISE STEREOCONTROLLED TOTAL SYNTHESIS OF (+)-ESTRONE
TAKANO, S
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[J]. TETRAHEDRON LETTERS, 1992, 33 (14) : 1909 - 1910
[9] EXPEDIENT PREPARATION AND ENANTIOMERIZATION OF OPTICALLY PURE DICYCLOPENTADIENONE (TRICYCLO[5.2.1.0(2,6)]DECA-4,8-DIEN-3-ONE)
TAKANO, S
INOMATA, K
TAKAHASHI, M
OGASAWARA, K
[J]. SYNLETT, 1991, (09) : 636 - 638
[10] ENANTIOCONVERGENT ROUTE TO ALPHA-CUPARENONE FROM DICYCLOPENTADIENE
TAKANO, S
INOMATA, K
OGASAWARA, K
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (05) : 271 - 272

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