A CONCISE STEREOCONTROLLED TOTAL SYNTHESIS OF (+)-ESTRONE

被引：56

作者：

TAKANO, S

MORIYA, M

OGASAWARA, K

机构：

[1] Pharmaceutical Institute, Tohoku University, Sendai, 980, Aobayama

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 14期

关键词：

D O I：

10.1016/S0040-4039(00)74175-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(+)-Estrone (1) has been synthesized in diastereo- and regioselective manners in six steps in 28% overall yield (38% based on the consumed material) starting from (-)-dicyclopentadienone (2) by employing a Diels-Alder cycloaddition-cycloreversion as the key step.

引用

页码：1909 / 1910

页数：2

共 23 条

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