DEPROTONATION OF 2-AMINOETHANETHIOL COMPLEXES OF NICKEL(II) AND PALLADIUM(II)

被引：13

作者：

WATT, GW

KNIFTON, JF

SENOFF, CV

机构：

[1] Department of Chemistry, University of Texas at Austin, Austin

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 11期

关键词：

D O I：

10.1021/ic50081a006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes M(SC3H4NH2)2 (M = Ni, Pd) are not deprotonated by anhydrous liquid ammonia at -33.5° but undergo successive deprotonation upon treatment with 1 and 2 molar equiv of amide ion in ammonia. The reprotonation and methylation of the resulting species are described and interpreted in relation to infrared spectral data. © 1969, American Chemical Society. All rights reserved.

引用

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