A ROTATING-DISK STUDY OF CROTYL ALCOHOL REDUCTION

被引：2

作者：

CHIEN, CY ^{[1
]}

SCHADE, G ^{[1
]}

机构：

[1] UNIV MISSOURI,DEPT CHEM,ROLLA,MO 65401

来源：

ELECTROCHIMICA ACTA | 1988年 / 33卷 / 01期

关键词：

BUTENES; -; ELECTROCHEMISTRY; ELECTRODES; Platinum; HYDROGEN; Oxidation; PARAFFINS;

D O I：

10.1016/0013-4686(88)80032-X

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Crotyl alcohol is reduced at a Pt-RRDE. Ring currents of hydrogen oxidation are used to calculate the partial current-voltage curves and Tafel slopes. Levich plots are used to support a two-stage mechanism. The intermediate, presumably butene, produced by electrochemical reduction is further reduced to the alkane by an electrocatalytic hydrogenation.

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页码：59 / 62

页数：4

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