MECHANISM OF THE PEROXYOXALATE CHEMILUMINESCENCE REACTION

被引：11

作者：

KWAKMAN, PJM

DEJONG, GJ

BRINKMAN, UAT

机构：

[1] Department of Analytical Chemistry, Free University, 1081 HV Amsterdam

来源：

TRAC-TRENDS IN ANALYTICAL CHEMISTRY | 1992年 / 11卷 / 07期

关键词：

D O I：

10.1016/0165-9936(92)87055-O

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

In recent years, much progress has been made in the development of high-performance liquid chromatographic (HPLC) detection systems based on peroxyoxalate chemiluminescence (CL) reactions. Peroxyoxalate CL is now one of the most sensitive detection methods in HPLC: for many compounds detection limits in the high femtogram/low picogram range have been obtained and a considerable number of applications have been reported. This paper discusses the complex and still not fully elucidated mechanism of peroxyoxalate CL.

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页码：232 / 237

页数：6

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