HIGHLY COORDINATED TIN HYDRIDES - A NOVEL SYNTHESIS OF TERTIARY-AMINES VIA HYDROSTANNATION OF IMINES

被引：46

作者：

KAWAKAMI, T ^{[1
]}

SUGIMOTO, T ^{[1
]}

SHIBATA, I ^{[1
]}

BABA, A ^{[1
]}

MATSUDA, H ^{[1
]}

SONODA, N ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1995年 / 60卷 / 09期

关键词：

D O I：

10.1021/jo00114a014

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The highly coordinated tin hydride, Bu(2)SnClH-HMPA (B), is shown to be an effective agent for the reduction of imines. The subsequent alkylation of the resulting intermediate tin amides permitted the preparation of a series of tertiary amines in a one-pot procedure. The spectral identification of the novel tin hydrides, B and Bu(2)SnClH-Bu(4)NF, was accomplished by H-1, C-13, and Sn-119 NMR and FT-IR studies.

引用

页码：2677 / 2682

页数：6

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