HIGHLY COORDINATED TIN HYDRIDES - A NOVEL SYNTHESIS OF TERTIARY-AMINES VIA HYDROSTANNATION OF IMINES

被引：46

作者：

KAWAKAMI, T ^{[1
]}

SUGIMOTO, T ^{[1
]}

SHIBATA, I ^{[1
]}

BABA, A ^{[1
]}

MATSUDA, H ^{[1
]}

SONODA, N ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1995年 / 60卷 / 09期

关键词：

D O I：

10.1021/jo00114a014

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The highly coordinated tin hydride, Bu(2)SnClH-HMPA (B), is shown to be an effective agent for the reduction of imines. The subsequent alkylation of the resulting intermediate tin amides permitted the preparation of a series of tertiary amines in a one-pot procedure. The spectral identification of the novel tin hydrides, B and Bu(2)SnClH-Bu(4)NF, was accomplished by H-1, C-13, and Sn-119 NMR and FT-IR studies.

引用

页码：2677 / 2682

页数：6

共 84 条

[61]

Holecek J., Nadvornik M., Handlir K., Lycka A., J. Organomet. Chem., 315, (1986)

[62]

Edlund U., Arshadi M., Johnels D., J. Organomet. Chem., 456, (1993)

[63]

Kuivila H.G., Dixon J.E., Maxfield P.L., Scarpa N.M., Topka T.M., Tsai K., Wursthorn K.R., J. Organomet. Chem., 86, (1975)

[64]

Chopa A.B., Koll L.C., Savini M.C., Podesta J.C., Neumann W.P., Organometallics, 4, (1985)

[65]

Ayala A.D., Giagante N., Podesta J.C., Neumann W.P., J. Organomet. Chem., 340, (1988)

[66]

Podesta J.C., Ayala A.D., Chopa A.B., Giagante N.N., J. Organomet. Chem., 364, (1989)

[67]

Barbieri G., Taddei F., J. Chem. Soc. Perkin Trans. 2, (1972)

[68]

McGardy M.M., Tobias R.S., J. Am. Chem. Soc., 87, (1965)

[69]

Molloy K.C., Blunden S.J., Hill R., J. Chem. Soc. Dalton Trans., (1988)

[70]

Maddox M.L., Flitcroft N., Kaesz H.D., J. Organomet. Chem., 4, (1965)

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