PHOTOCHEMISTRY OF PERMETHYLOLIGOSILANES

被引：8

作者：

DAVIDSON, IMT ^{[1
]}

MICHL, J ^{[1
]}

SIMPSON, T ^{[1
]}

机构：

[1] UNIV TEXAS,DEPT CHEM,CTR STRUCT & REACT,AUSTIN,TX 78712

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 04期

关键词：

D O I：

10.1021/om00050a009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Primary photochemical pathways have been identified in the irradiation of three oligosilanes at 254 nm. These pathways include a reductive elimination not previously observed in oligosilanes but closely analogous to a chain-scission process that has been observed in polysilane materials.

引用

页码：842 / 844

页数：3

共 12 条

[1] FORMATION OF CYCLIC CARBOSILANES IN THE PYROLYSIS OF OCTAMETHYLTRISILANE [J].

BORTOLIN, BN ;

DAVIDSON, IMT ;

LANCASTER, D ;

SIMPSON, T ;

WILD, DA .

ORGANOMETALLICS, 1990, 9 (01) :281-284

[2] STATIONARY AND PULSED PHOTOLYSIS OF HEXAMETHYLDISILANE [J].

BRIX, T ;

BASTIAN, E ;

POTZINGER, P .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1989, 49 (03) :287-297

[3] PHOTOLYSIS OF DODECAMETHYLCYCLOHEXASILANE - GENERATION OF DIMETHYLSILYLENE AND SOME OF ITS INSERTION REACTIONS [J].

ISHIKAWA, M ;

KUMADA, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 42 (02) :325-&

[4] PHOTOLYSIS OF PERMETHYLATED LINEAR AND BRANCHED-CHAIN POLYSILANES [J].

ISHIKAWA, M ;

KUMADA, M .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1971, (10) :489-&

[5] MECHANISM OF THE PHOTOCHEMICAL DEGRADATION OF POLY(DI-NORMAL-ALKYLSILANES) IN SOLUTION [J].

KARATSU, T ;

MILLER, RD ;

SOORIYAKUMARAN, R ;

MICHL, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (03) :1140-1141

[6] LASER DESORPTION MASS-SPECTROMETRY OF POLYSILANES [J].

MAGNERA, TF ;

BALAJI, V ;

MICHL, J ;

MILLER, RD ;

SOORIYAKUMARAN, R .

MACROMOLECULES, 1989, 22 (04) :1624-1635

[7] PHOTODEGRADATION OF POLY(DIALKYLSILANE)S IN SOLUTION - THE PERSISTENT RADICALS HAVE AN UNEXPECTED STRUCTURE [J].

MCKINLEY, AJ ;

KARATSU, T ;

WALLRAFF, GM ;

MILLER, RD ;

SOORIYAKUMARAN, R ;

MICHL, J .

ORGANOMETALLICS, 1988, 7 (12) :2567-2569

[8]

MCKINLEY AJ, IN PRESS J AM CHEM S

[9] POLYSILANE HIGH POLYMERS [J].

MILLER, RD ;

MICHL, J .

CHEMICAL REVIEWS, 1989, 89 (06) :1359-1410

[10] POLYSILANE HIGH POLYMERS - MECHANISM OF PHOTODEGRADATION [J].

TREFONAS, P ;

WEST, R ;

MILLER, RD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (09) :2737-2742

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