KINETICS OF PHOTOCURRENT GENERATION AND QUANTUM EFFICIENCY OF A DYE SENSITIZED PLATINIZED SOLID-STATE PHOTOVOLTAIC CELL MADE FROM P-TYPE CUCNS AND N-SNO2 TRANSPARENT FILM ON GLASS

被引:10
作者
FERNANDO, CAN [1 ]
机构
[1] UNIV RUHUNA,DEPT PHYS,MATARA,SRI LANKA
关键词
D O I
10.1016/0927-0248(92)90034-M
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The mechanism of photocurrent enhancement of a platinized dye sensitized solid state photovoltaic cell based on p-CuCNS and SnO2 coated transparent glass is discussed. The variation of photocurrent quantum efficiency (phi) with dye concentration (D0) of the device is presented for both platinized and unplatinized systems. According to the experimental results the parameters A and B in the model equation phi = AD0 - BD0(2) are calculated. It is found that parameter B is decreased and parameter A is increased for platinized systems compared with unplatinized systems. Photocurrent enhancement due to platinization is further discussed with the photophysical processes and charge transfer processes associated with the device.
引用
收藏
页码:255 / 271
页数:17
相关论文
共 26 条
[1]  
BICKLEY RI, 1988, CATALYSIS, pL1
[2]  
FUJIHARA M, 1987, J ELECTROCHEM SOC, V88, P285
[3]  
GARAJ J, 1965, CHEM ZVESTI, V19, P593
[4]  
ITOH K, 1984, J AM CHEM SOC, V106, P1630
[5]   CRYSTAL-STRUCTURE OF COPPER(I) THIOCYANATE AND ITS RELATION TO CRYSTAL-STRUCTURE OF COPPER(II) DIAMMINE DITHIOCYANATE COMPLEX [J].
KABESOVA, M ;
DUNAJJURCO, M ;
SERATOR, M ;
GAZO, J ;
GARAJ, J .
INORGANICA CHIMICA ACTA, 1976, 17 (02) :161-165
[6]  
KRUGER D, 1941, CHEM BER B, V74, P1378
[7]  
LOUFTY RO, 1981, J APPL PHYS, V52, P5218
[8]   ORGANIC SOLAR-CELLS OF HYDROXY SQUARYLIUM [J].
MERRITT, VY ;
HOVEL, HJ .
APPLIED PHYSICS LETTERS, 1976, 29 (07) :414-415
[9]  
MERRITT YY, 1976, APPL PHYS LETT, V414, P29
[10]  
NAKAO M, 1984, J PHYS CHEM-US, V88, P4907