ADDUCTS OF INCL3, WITH LEWIS-BASES - CRYSTAL AND MOLECULAR-STRUCTURE OF [(INCL3)(2)(DME)(3)]

被引：11

作者：

CARTA, G ^{[1
]}

BENETOLLO, F ^{[1
]}

SITRAN, S ^{[1
]}

ROSSETTO, G ^{[1
]}

BRAGA, F ^{[1
]}

ZANELLA, P ^{[1
]}

机构：

[1] CNR, IST CHIM & TECNOL INORGAN & MAT AVANZATI, AREA RIC, I-35127 PADUA, ITALY

来源：

POLYHEDRON | 1995年 / 14卷 / 13-14期

关键词：

D O I：

10.1016/0277-5387(94)00449-O

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A number of adducts of InCl3 with selected Lewis bases have been synthesized and characterized. The complex of InCl3 with 1,2-dimethoxyethane (DME = CH3OCH2CH2OCH3) is characterized by two centrosymmetrically related InCl3 . DME . 0.5 DME units, where the indium is six-coordinated to three chlorine atoms, two oxygen atoms of one chelating DME unit and one oxygen atom of the bridging DME ligand in a fac-octahedral arrangement. The suitability and limits of using InCl3 . 3/2DME for the synthesis of InMe(3) (Me = CH3) are discussed.

引用

页码：1923 / 1928

页数：6

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