PALLADIUM-ASSISTED (Z)-(E) ISOMERIZATION OF STYRENES

被引:33
作者
GILES, RGF
SON, VRL
SARGENT, MV
机构
[1] UNIV WESTERN AUSTRALIA,DEPT ORGAN CHEM,NEDLANDS,AUSTRALIA
[2] UNIV CAPE TOWN,DEPT ORGAN CHEM,RONDEBOSCH 7700,SOUTH AFRICA
关键词
D O I
10.1071/CH9900777
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
It is shown that treatment of stereoisomeric mixtures of styrenes with a catalytic amount of bis(acetonitrile)dichloropalladium(11) achieves smooth stereoisomerization of the (Z)-isomers to the (E)-isomers. © 1990 ASEG.
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页码:777 / 781
页数:5
相关论文
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[21]  
TROST BM, 1982, COMPREHENSIVE ORGANO, V8, P802