SYNTHESIS OF A CHIRAL BINAPHTHYLDISULFIDE - A POTENTIALLY USEFUL REAGENT FOR CATALYTIC ASYMMETRIC-SYNTHESIS

被引：15

作者：

FELDMAN, KS

RUCKLE, RE

ENSEL, SM

WEINREB, PH

机构：

[1] Chemistry Department, The Pennsylvania State University University Park

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 47期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(00)60846-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Diels Alder cycloaddition/oxygen-atom-extrusion provides the means to unite two naphthylene fragments and affords a highly functionalized, racemic binaphthyl iodide. Resolution of a derived thiol then furnishes, after appropriate manipulation, enantiomerically pure binaphthyldisulfide precatalysts.

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收藏

页码：7101 / 7102

页数：2

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