ENANTIOSELECTIVE CATALYTIC INTRAMOLECULAR CYCLOPROPANATION OF ALLYLIC ALPHA-DIAZOPROPIONATES OPTIMIZED WITH DIRHODIUM(II) TETRAKIS[METHYL 2-OXAZOLIDINONE-4(S OR R)CARBOXYLATE]

被引：28

作者：

DOYLE, MP

ZHOU, QL

机构：

[1] Department of Chemistry, Trinity University, San Antonio

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 09期

关键词：

D O I：

10.1016/0957-4166(95)00289-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

High enantiocontrol, up to 85% ee, has been achieved in intramolecular cyclopropanation reactions of representative allylic alpha-diazopropionates with the catalytic uses of Rh-2(4S-MEOX)(4).

引用

页码：2157 / 2160

页数：4

共 17 条

[1] ENANTIOSELECTIVELY CATALYZED INTRAMOLECULAR CYCLOPROPANATIONS OF UNSATURATED DIAZO CARBONYL-COMPOUNDS
DAUBEN, WG
HENDRICKS, RT
LUZZIO, MJ
NG, HP
[J]. TETRAHEDRON LETTERS, 1990, 31 (48) : 6969 - 6972
[2] DOYLE MP, 1995, RECL TRAV CHIM PAY B, V114, P163
[3] DIRHODIUM(II) TETRAKIS(CARBOXAMIDATES) WITH CHIRAL LIGANDS - STRUCTURE AND SELECTIVITY IN CATALYTIC METAL CARBENE TRANSFORMATIONS
DOYLE, MP
WINCHESTER, WR
HOORN, JAA
LYNCH, V
SIMONSEN, SH
GHOSH, R
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (22) : 9968 - 9978
[4] ENANTIOSELECTIVE INTRAMOLECULAR CYCLOPROPANATIONS OF ALLYLIC AND HOMOALLYLIC DIAZOACETATES AND DIAZOACETAMIDES USING CHIRAL DIRHODIUM(II) CARBOXAMIDE CATALYSTS
DOYLE, MP
AUSTIN, RE
BAILEY, AS
DWYER, MP
DYATKIN, AB
KALININ, AV
KWAN, MMY
LIRAS, S
OALMANN, CJ
PIETERS, RJ
PROTOPOPOVA, MN
RAAB, CE
ROOS, GHP
ZHOU, QL
MARTIN, SF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (21) : 5763 - 5775
[5] DOYLE MP, 1993, CATALYTIC ASYMMETRIC
[6] ENANTIOSELECTIVE INTRAMOLECULAR C-H INSERTION OF ALPHA-DIAZO BETA-KETO-ESTERS CATALYZED BY HOMOCHIRAL RHODIUM(II) CARBOXYLATES
HASHIMOTO, S
WATANABE, N
IKEGAMI, S
[J]. TETRAHEDRON LETTERS, 1990, 31 (36) : 5173 - 5174
[7] DOUBLE ASYMMETRIC INDUCTION IN INTRAMOLECULAR C-H INSERTION REACTIONS OF ALPHA-DIAZO BETA-KETO-ESTERS
HASHIMOTO, S
WATANABE, N
KAWANO, K
IKEGAMI, S
[J]. SYNTHETIC COMMUNICATIONS, 1994, 24 (22) : 3277 - 3287
[8] SYNTHESIS OF BETA-METHOXY ENONES VIA A NEW 2-CARBON EXTENSION OF CARBOXYLIC-ACIDS
HUDLICKY, T
OLIVO, HF
NATCHUS, MG
UMPIERREZ, EF
PANDOLFI, E
VOLONTERIO, C
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (15) : 4767 - 4770
[9] ASYMMETRIC-SYNTHESIS IN CARBON CARBON BOND FORMING REACTIONS OF ALPHA-DIAZOKETONES CATALYZED BY HOMOCHIRAL RHODIUM(II) CARBOXYLATES
KENNEDY, M
MCKERVEY, MA
MAGUIRE, AR
ROOS, GHP
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (05) : 361 - 362
[10] ASYMMETRIC CATALYSIS IN INTRAMOLECULAR CYCLOPROPANATION
KOSKINEN, AMP
HASSILA, H
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (16) : 4479 - 4480

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