RUBBER-LIKE ELASTICITY OF ORGANICALLY MODIFIED SILICATES

被引：73

作者：

HU, Y

MACKENZIE, JD

机构：

[1] Department of Materials Science and Engineering, University of California Los Angeles, Los Angeles, 90024, CA

来源：

JOURNAL OF MATERIALS SCIENCE | 1992年 / 27卷 / 16期

关键词：

D O I：

10.1007/BF00541574

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Rubber-like stress-strain behaviour was observed in the organically modified silicates (ORMOSILS) in which tetraethoxysilane (TEOS) and polydimethyl siloxane (PDMS) were used as the inorganic and polymeric components, respectively. The flexibility and rubber-like elasticity of ORMOSILS increase with increasing volume fraction of incorporated PDMS. When the nominal mass ratio of TEOS/PDMS was less than 1.5, the ORMOSILS began to show the rubber-like elasticity. Three conceptual models of the structure of ORMOSILS that results from the fundamental reaction between TEOS and PDMS were used to interpret the experimental results.

引用

页码：4415 / 4420

页数：6