ACID-CATALYZED HYDROLYSIS AND PROTONATION BEHAVIOR OF N-ARYLPROPANE-1,3-SULTAMS

被引：14

作者：

BEKDEMIR, Y

TILLETT, JG

ZALEWSKI, RI

机构：

[1] UNIV ESSEX,DEPT CHEM & BIOL CHEM,COLCHESTER CO4 3SQ,ESSEX,ENGLAND

[2] ACAD ECON POZNAN,DEPT GEN & ANALYT CHEM,POZNAN,POLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1993年 / 09期

关键词：

D O I：

10.1039/p29930001643

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The acid-catalysed hydrolyses of some N-(para-substituted phenyl)propane-1,3-sultams have been studied in aqueous acidic solutions. The rate maxima observed are shown to be consistent with an A-2 mechanism in which extensive protonation of the substrate occurs. Values of pK(BH+) for the sultams have been determined.

引用

收藏

页码：1643 / 1646

页数：4

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