N-[BIS(METHYLTHIO)METHYLENE]-DIDEHYDROALANINE METHYL-ESTER A NEW AND EXCELLENT DIENOPHILE FOR THE SYNTHESIS OF 2-AMINONORBORNENE-2-CARBOXYLIC ACID

被引：4

作者：

BUNUEL, E ^{[1
]}

CATIVIELA, C ^{[1
]}

DIAZDEVILLEGAS, MD ^{[1
]}

机构：

[1] UNIV ZARAGOZA,CSIC,INST CIENCIA MAT ARAGON,DEPT QUIM ORGAN,E-50009 ZARAGOZA,SPAIN

来源：

TETRAHEDRON | 1993年 / 49卷 / 33期

关键词：

D O I：

10.1016/S0040-4020(01)87206-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-[Bis(methylthio)methylene]-didehydroalanine methyl ester behaves as an excellent dienophile with cyclopentadiene to afford methyl N-[Bis(methylthio)methylene]-2-aminonorbornene-2-carboxylate in excellent yield and with high selectivity.

引用

页码：7287 / 7294

页数：8

共 14 条

[1] DIELS-ALDER REACTIONS OF METHYL-N-ACYL-ALPHA,BETA-DEHYDROALANINATES WITH CYCLOPENTADIENE
BUENO, MP
CATIVIELA, C
FINOL, C
MAYORAL, JA
JAIME, C
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1987, 65 (09): : 2182 - 2186
[2] BUNUEL E, 1992, SYNLETT, P579
[3] ETHYL 2-(DIPHENYLMETHYLENEAMINO)ACRYLATE AS A DIENOPHILE IN THE SYNTHESIS OF ALICYCLIC ALPHA-AMINO-ACIDS
CATIVIELA, C
FRAILE, JM
MAYORAL, JA
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1990, 63 (08) : 2456 - 2457
[4] ASYMMETRIC-SYNTHESIS OF 2-AMINONORBORNANE-2-CARBOXYLIC ACIDS BY DIELS-ALDER REACTION
CATIVIELA, C
LOPEZ, P
MAYORAL, JA
[J]. TETRAHEDRON-ASYMMETRY, 1990, 1 (02) : 61 - 64
[5] ASYMMETRIC-SYNTHESIS OF 2-EXO-AMINONORBORNANE-2-ENDO-CARBOXYLIC ACID-DERIVATIVES
CATIVIELA, C
LOPEZ, P
MAYORAL, JA
[J]. TETRAHEDRON-ASYMMETRY, 1991, 2 (06) : 449 - 456
[6] ASYMMETRIC-SYNTHESIS OF CYCLOALIPHATIC ALPHA-AMINO-ACIDS WITH A NORBORNANE SKELETON
CATIVIELA, C
LOPEZ, P
MAYORAL, JA
[J]. TETRAHEDRON-ASYMMETRY, 1990, 1 (06) : 379 - 388
[7] ASYMMETRIC-SYNTHESIS OF 2-AMINONORBORNANE-2-CARBOXYLIC ACIDS BY DIELS-ALDER REACTION
CATIVIELA, C
LOPEZ, P
MAYORAL, JA
[J]. TETRAHEDRON-ASYMMETRY, 1991, 2 (12) : 1295 - 1304
[8] STEREOSPECIFIC SYNTHESIS OF N-[BIS(METHYLTHIO)METHYLENE]-ALPHA,BETA-DIDEHYDROAMINO ACID METHYL-ESTERS, NEW SYNTHONS IN THE SYNTHESIS OF ALPHA-AMINO-ACIDS
CATIVIELA, C
DEVILLEGAS, MDD
[J]. TETRAHEDRON, 1993, 49 (02) : 497 - 506
[9] CHRISTENSEN HN, 1969, J BIOL CHEM, V244, P1521
[10] CHRISTENSEN HN, 1969, J BIOL CHEM, V244, P1510

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