SMALL RINGS .81. RING-OPENING OF CYCLOPROPANE AT 10 K

被引：23

作者：

MAIER, G

SENGER, S

机构：

[1] Institut für Organische Chemie, Universität Giessen, D-35392

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 05期

关键词：

D O I：

10.1002/anie.199405581

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

“Thermal” reactions at 10 K? How is it posible to achieve a thermal ring‐opening of cyclopropane [Eq. (a)] and cyclopropene (both reactions have substantial energy barriers) at such extremely low temperatures? The answer is to be found in this communications. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

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页码：558 / 559

页数：2

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