HIGHLY REGIOSELECTIVE PALLADIUM-MEDIATED SUBSTITUTION OF ALLYLIC AND DIENYLIC CYCLIC CARBONATES

被引：39

作者：

KANG, SK

PARK, DC

JEON, JH

RHO, HS

YU, CM

机构：

[1] Department of Chemistry, Sung Kyun Kwan University, Suwon, 440-746, Natural Science Campus

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 15期

关键词：

D O I：

10.1016/0040-4039(94)85219-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of chiral allylic and dienylic cyclic carbonates with various nucleophiles in the presence of (PPh(3))(4)Pd as a catalyst afforded alpha-, gamma-, or epsilon-substituted products with high regio-, (E)-stereo-, and diastereoselectivity depending on nucleophiles.

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页码：2357 / 2360

页数：4

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