INCLUSION-COMPOUNDS OF DERIVATIZED AMYLOSES

被引：27

作者：

KUBIK, S ^{[1
]}

HOLLER, O ^{[1
]}

STEINERT, A ^{[1
]}

TOLKSDORF, M ^{[1
]}

WULFF, G ^{[1
]}

机构：

[1] UNIV DUSSELDORF,INST ORGAN CHEM & MAKROMOLEK CHEM,D-40225 DUSSELDORF,GERMANY

来源：

MACROMOLECULAR SYMPOSIA | 1995年 / 99卷

关键词：

D O I：

10.1002/masy.19950990111

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Inclusion complexes of slightly hydroxypropylated amylose with organic guest molecules have been investigated by means of c.d. spectroscopy and microcalorimetry in aqueous solution. From these results, the structure of the complexes and the mechanism of their fomation are deduced. It is concluded that amylose can adjust its helix conformation to the shape and structure of the guest molecule included. Investigations about intramolecular and intermolecular crosslinking of amylose indicate that the complexing behavior of amylose can be manipulated specifically.

引用

页码：93 / 102

页数：10