THE REACTION OF PTCL2 WITH AN N,S,O-COORDINATED CALCIUM COMPLEX - SYNTHESIS AND STRUCTURE OF A COMPLEXED CAPT ANION

被引：16

作者：

DAVIDSON, MG ^{[1
]}

RAITHBY, PR ^{[1
]}

SNAITH, R ^{[1
]}

STALKE, D ^{[1
]}

WRIGHT, DS ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 12期

关键词：

D O I：

10.1002/anie.199116481

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A Ca2 complex cation combines with the Ca-Pt complex anion (shown right) to form the salt 1. It is obtained from a reaction of solid PtCl2 with [Ox2Ca(HMPA)2] in toluene under reflux. The complex anion can be considered a model for heteronuclear catalysts and for adducts of Pt2+ with DNA bases.

引用

页码：1648 / 1650

页数：3

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