Numerous greenstone relies, all containing the two lowermost formations of the Onverwacht Group, occur in the Archean trondhjemitic/tonalitic gneiss terrains south of the Barberton Greenstone Belt. In this study, we report detailed petrological, geochemical, and isotopic (Nd, O, H, 40Ar/39Ar) data obtained on komatiites from the Schapenburg Greenstone Remnant (SGR), the largest and best-preserved greenstone relic. The main goals are(l)to date the metamorphism affecting the SGR using the 40Ar/ 39Ar dating method on amphiboles, (2) to evaluate the effect of metamorphism on the preservation of primary isotopic and chemical signatures, and (3) to estimate the temperature and water/rock ratios that prevailed during metamorphic recrystallization in order to constrain the composition and origin of the reacting fluid phase. 40Ar/39Ar ages of 2.9 Ga obtained on two amphibole separates from the Schapenburg metavolcanics reveal the existence of a metamorphic event younger than the emplacement age (3.5 Ga). This metamorphic event belongs to a series of discrete periods of thermal activity from 3.4 to 2 Ga, each of which coincides with a major episode of magmatic activity. The ultrabasic lava flows acquired their delta(18)O values (from +3.2 to +5 parts per thousand) at high temperature (approximate to 450 degrees C) under high water/rock ratios. The reacting water had initial isotopic Values typical of metamorphic fluids (delta(18)O = +5 to +7 parts per thousand; delta D = -65 to -50 parts per thousand). REE patterns were not disturbed by metamorphic recrystallization. Despite the long time interval between emplacement and metamorphism (approximate to 600 Ma), epsilon(Nd)(T) values are uniform throughout the whole magmatic suite, indicating that the Sm-Nd system was closed on the sample scale during metamorphism. The mantle source of these greenstones was depleted in LREE as evidence by epsilon(Nd)(T) approximate to +2.5. Chemical fluxes during metamorphism were calculated for elements unfractionated by olivine removal (e.g. Na, Ca, Ti, Al, and Sr), by normalizing to Nd. They suggest a significant mobility of most major elements in the cumulate zones of the lava flows. By contrast, spinifex zones appear to have preserved most of their primary chemical signatures during metamorphic recrystallization. Their CaO/Al2O3 and Al2O3/TiO2 ratios can be used with confidence to determine the PT conditions of melting in the mantle source. A general model of water-rock interactions applied to the sedimentary and magmatic rocks of the Onverwacht Group is also presented. The model involves conditions of metamorphism deduced from this study and available data from the literature. In addition to metavolcanic rocks, most of the oxygen isotope compositions of carbonates and cherts (except the highest values) can be explained by reequilibration with metamorphic fluids under greenschist-amphibolite facies conditions. Numerous greenstone relies, all containing the two lowermost formations of the Onverwacht Group, occur in the Archean trondhjemitic/tonalitic gneiss terrains south of the Barberton Greenstone Belt. In this study, we report detailed petrological, geochemical, and isotopic (Nd, O, H, 40Ar/39Ar) data obtained on komatiites from the Schapenburg Greenstone Remnant (SGR), the largest and best-preserved greenstone relic. The main goals are(l)to date the metamorphism affecting the SGR using the 40Ar/ 39Ar dating method on amphiboles, (2) to evaluate the effect of metamorphism on the preservation of primary isotopic and chemical signatures, and (3) to estimate the temperature and water/rock ratios that prevailed during metamorphic recrystallization in order to constrain the composition and origin of the reacting fluid phase. 40Ar/39Ar ages of 2.9 Ga obtained on two amphibole separates from the Schapenburg metavolcanics reveal the existence of a metamorphic event younger than the emplacement age (3.5 Ga). This metamorphic event belongs to a series of discrete periods of thermal activity from 3.4 to 2 Ga, each of which coincides with a major episode of magmatic activity. The ultrabasic lava flows acquired their delta(18)O values (from +3.2 to +5 parts per thousand) at high temperature (approximate to 450 degrees C) under high water/rock ratios. The reacting water had initial isotopic Values typical of metamorphic fluids (delta(18)O = +5 to +7 parts per thousand; delta D = -65 to -50 parts per thousand). REE patterns were not disturbed by metamorphic recrystallization. Despite the long time interval between emplacement and metamorphism (approximate to 600 Ma), epsilon(Nd)(T) values are uniform throughout the whole magmatic suite, indicating that the Sm-Nd system was closed on the sample scale during metamorphism. The mantle source of these greenstones was depleted in LREE as evidence by epsilon(Nd)(T) approximate to +2.5. Chemical fluxes during metamorphism were calculated for elements unfractionated by olivine removal (e.g. Na, Ca, Ti, Al, and Sr), by normalizing to Nd. They suggest a significant mobility of most major elements in the cumulate zones of the lava flows. By contrast, spinifex zones appear to have preserved most of their primary chemical signatures during metamorphic recrystallization. Their CaO/Al2O3 and Al2O3/TiO2 ratios can be used with confidence to determine the PT conditions of melting in the mantle source. A general model of water-rock interactions applied to the sedimentary and magmatic rocks of the Onverwacht Group is also presented. The model involves conditions of metamorphism deduced from this study and available data from the literature. In addition to metavolcanic rocks, most of the oxygen isotope compositions of carbonates and cherts (except the highest values) can be explained by reequilibration with metamorphic fluids under greenschist-amphibolite facies conditions. Numerous greenstone relies, all containing the two lowermost formations of the Onverwacht Group, occur in the Archean trondhjemitic/tonalitic gneiss terrains south of the Barberton Greenstone Belt. In this study, we report detailed petrological, geochemical, and isotopic (Nd, O, H, 40Ar/39Ar) data obtained on komatiites from the Schapenburg Greenstone Remnant (SGR), the largest and best-preserved greenstone relic. The main goals are(l)to date the metamorphism affecting the SGR using the 40Ar/ 39Ar dating method on amphiboles, (2) to evaluate the effect of metamorphism on the preservation of primary isotopic and chemical signatures, and (3) to estimate the temperature and water/rock ratios that prevailed during metamorphic recrystallization in order to constrain the composition and origin of the reacting fluid phase. 40Ar/39Ar ages of 2.9 Ga obtained on two amphibole separates from the Schapenburg metavolcanics reveal the existence of a metamorphic event younger than the emplacement age (3.5 Ga). This metamorphic event belongs to a series of discrete periods of thermal activity from 3.4 to 2 Ga, each of which coincides with a major episode of magmatic activity. The ultrabasic lava flows acquired their delta(18)O values (from +3.2 to +5 parts per thousand) at high temperature (approximate to 450 degrees C) under high water/rock ratios. The reacting water had initial isotopic Values typical of metamorphic fluids (delta(18)O = +5 to +7 parts per thousand; delta D = -65 to -50 parts per thousand). REE patterns were not disturbed by metamorphic recrystallization. Despite the long time interval between emplacement and metamorphism (approximate to 600 Ma), epsilon(Nd)(T) values are uniform throughout the whole magmatic suite, indicating that the Sm-Nd system was closed on the sample scale during metamorphism. The mantle source of these greenstones was depleted in LREE as evidence by epsilon(Nd)(T) approximate to +2.5. Chemical fluxes during metamorphism were calculated for elements unfractionated by olivine removal (e.g. Na, Ca, Ti, Al, and Sr), by normalizing to Nd. They suggest a significant mobility of most major elements in the cumulate zones of the lava flows. By contrast, spinifex zones appear to have preserved most of their primary chemical signatures during metamorphic recrystallization. Their CaO/Al2O3 and Al2O3/TiO2 ratios can be used with confidence to determine the PT conditions of melting in the mantle source. A general model of water-rock interactions applied to the sedimentary and magmatic rocks of the Onverwacht Group is also presented. The model involves conditions of metamorphism deduced from this study and available data from the literature. In addition to metavolcanic rocks, most of the oxygen isotope compositions of carbonates and cherts (except the highest values) can be explained by reequilibration with metamorphic fluids under greenschist-amphibolite facies conditions. Numerous greenstone relies, all containing the two lowermost formations of the Onverwacht Group, occur in the Archean trondhjemitic/tonalitic gneiss terrains south of the Barberton Greenstone Belt. In this study, we report detailed petrological, geochemical, and isotopic (Nd, O, H, 40Ar/39Ar) data obtained on komatiites from the Schapenburg Greenstone Remnant (SGR), the largest and best-preserved greenstone relic. The main goals are(l)to date the metamorphism affecting the SGR using the 40Ar/ 39Ar dating method on amphiboles, (2) to evaluate the effect of metamorphism on the preservation of primary isotopic and chemical signatures, and (3) to estimate the temperature and water/rock ratios that prevailed during metamorphic recrystallization in order to constrain the composition and origin of the reacting fluid phase. 40Ar/39Ar ages of 2.9 Ga obtained on two amphibole separates from the Schapenburg metavolcanics reveal the existence of a metamorphic event younger than the emplacement age (3.5 Ga). This metamorphic event belongs to a series of discrete periods of thermal activity from 3.4 to 2 Ga, each of which coincides with a major episode of magmatic activity. The ultrabasic lava flows acquired their delta(18)O values (from +3.2 to +5 parts per thousand) at high temperature (approximate to 450 degrees C) under high water/rock ratios. The reacting water had initial isotopic Values typical of metamorphic fluids (delta(18)O = +5 to +7 parts per thousand; delta D = -65 to -50 parts per thousand). REE patterns were not disturbed by metamorphic recrystallization. Despite the long time interval between emplacement and metamorphism (approximate to 600 Ma), epsilon(Nd)(T) values are uniform throughout the whole magmatic suite, indicating that the Sm-Nd system was closed on the sample scale during metamorphism. The mantle source of these greenstones was depleted in LREE as evidence by epsilon(Nd)(T) approximate to +2.5. Chemical fluxes during metamorphism were calculated for elements unfractionated by olivine removal (e.g. Na, Ca, Ti, Al, and Sr), by normalizing to Nd. They suggest a significant mobility of most major elements in the cumulate zones of the lava flows. By contrast, spinifex zones appear to have preserved most of their primary chemical signatures during metamorphic recrystallization. Their CaO/Al2O3 and Al2O3/TiO2 ratios can be used with confidence to determine the PT conditions of melting in the mantle source. A general model of water-rock interactions applied to the sedimentary and magmatic rocks of the Onverwacht Group is also presented. The model involves conditions of metamorphism deduced from this study and available data from the literature. In addition to metavolcanic rocks, most of the oxygen isotope compositions of carbonates and cherts (except the highest values) can be explained by reequilibration with metamorphic fluids under greenschist-amphibolite facies conditions. Numerous greenstone relies, all containing the two lowermost formations of the Onverwacht Group, occur in the Archean trondhjemitic/tonalitic gneiss terrains south of the Barberton Greenstone Belt. In this study, we report detailed petrological, geochemical, and isotopic (Nd, O, H, 40Ar/39Ar) data obtained on komatiites from the Schapenburg Greenstone Remnant (SGR), the largest and best-preserved greenstone relic. The main goals are(l)to date the metamorphism affecting the SGR using the 40Ar/ 39Ar dating method on amphiboles, (2) to evaluate the effect of metamorphism on the preservation of primary isotopic and chemical signatures, and (3) to estimate the temperature and water/rock ratios that prevailed during metamorphic recrystallization in order to constrain the composition and origin of the reacting fluid phase. 40Ar/39Ar ages of 2.9 Ga obtained on two amphibole separates from the Schapenburg metavolcanics reveal the existence of a metamorphic event younger than the emplacement age (3.5 Ga). This metamorphic event belongs to a series of discrete periods of thermal activity from 3.4 to 2 Ga, each of which coincides with a major episode of magmatic activity. The ultrabasic lava flows acquired their delta(18)O values (from +3.2 to +5 parts per thousand) at high temperature (approximate to 450 degrees C) under high water/rock ratios. The reacting water had initial isotopic Values typical of metamorphic fluids (delta(18)O = +5 to +7 parts per thousand; delta D = -65 to -50 parts per thousand). REE patterns were not disturbed by metamorphic recrystallization. Despite the long time interval between emplacement and metamorphism (approximate to 600 Ma), epsilon(Nd)(T) values are uniform throughout the whole magmatic suite, indicating that the Sm-Nd system was closed on the sample scale during metamorphism. The mantle source of these greenstones was depleted in LREE as evidence by epsilon(Nd)(T) approximate to +2.5. Chemical fluxes during metamorphism were calculated for elements unfractionated by olivine removal (e.g. Na, Ca, Ti, Al, and Sr), by normalizing to Nd. They suggest a significant mobility of most major elements in the cumulate zones of the lava flows. By contrast, spinifex zones appear to have preserved most of their primary chemical signatures during metamorphic recrystallization. Their CaO/Al2O3 and Al2O3/TiO2 ratios can be used with confidence to determine the PT conditions of melting in the mantle source. A general model of water-rock interactions applied to the sedimentary and magmatic rocks of the Onverwacht Group is also presented. The model involves conditions of metamorphism deduced from this study and available data from the literature. In addition to metavolcanic rocks, most of the oxygen isotope compositions of carbonates and cherts (except the highest values) can be explained by reequilibration with metamorphic fluids under greenschist-amphibolite facies conditions.
