DEVIATION FROM CURIE-WEISS BEHAVIOR IN RELAXOR FERROELECTRICS

被引:536
作者
VIEHLAND, D
JANG, SJ
CROSS, LE
WUTTIG, M
机构
[1] UNIV ILLINOIS,DEPT MAT SCI & ENGN,URBANA,IL 61801
[2] PENN STATE UNIV,MAT RES LAB,UNIV PK,PA 16802
[3] UNIV MARYLAND,DEPT MAT & NUCL ENGN,COLL PK,MD 20742
[4] PENN STATE UNIV,DEPT ELECT ENGN,UNIV PK,PA 16802
来源
PHYSICAL REVIEW B | 1992年 / 46卷 / 13期
关键词
D O I
10.1103/PhysRevB.46.8003
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The deviation from Cure-Weiss behavior has been investigated in lead magnesium niobate relaxor ferroelectrics. At high temperatures, the susceptibility was found to follow the Curie-Weiss relationship. A Curie constant and temperature of 1.2 x 10(5) and 398 K, respectively, were obtained. With decreasing temperature the deviation was found to increase. It is proposed that this deviation arises due to short-range correlations between polar regions, and that these correlations at high temperatures are the precursor to a freezing of the polarization fluctuations into a glassy state. A local (glassy) order parameter was calculated from the susceptibility by analogy to spin glasses [D. Sherrington and S. Kirkpatrick, Phys. Rev. Lett. 35, 1972 (1975)]. These results are compared to the rms polarization [G. Burns and F. Dacol, Solid State Commun. 48, 853 (1983)] and to the measured remanent polarization. The frequency and field dependence has also been investigated.
引用
收藏
页码:8003 / 8006
页数:4
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