MAGNETIC SHIELDING OF A HYDROGEN MOLECULE IN AN ELECTRIC FIELD

被引：14

作者：

GRUNINGE.J

HAMEKA, HF

机构：

[1] Department of Chemistry, University of Pennsylvania, Philadelphia, PA

[2] Department of Chemistry, West Virginia University, Morgantown, WV

来源：

JOURNAL OF CHEMICAL PHYSICS | 1968年 / 48卷 / 11期

关键词：

D O I：

10.1063/1.1668119

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We evaluate the effect of an electric field F along the molecular axis on the magnetic shielding constants σa and σb of a hydrogen molecule. It was found that the two shielding constants can be represented as σa,b(F)=σ±C1F z - C3Fx2 C3F x2-C3Fx2-C′2(F x2+Fy2) if the z axis is taken as the molecular axis. We found that σ = 1.40114σ0 and C1 = 2.19171σ0 if F is expressed in atomic units e/a02; σ0=e2/3mc 2a0. It is concluded that the splitting is observable if F is of the order of 106 to 107 V/cm.

引用

页码：4878 / &

共 21 条

[11] The quantic theory of inter-atomic currents in aromatic combinations. [J].