ETHYLENE THIONOCATBONATE AND 1,3-OXATHIOLANE-2-THIONE

被引：56

作者：

JONES, FN

ANDREADE.S

机构：

[1] Central Research Department, Experimental Station, E. I. du Pont de Nemours and Company, Wilmington

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 10期

关键词：

D O I：

10.1021/jo01262a047

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Synthesis and reactions of the title compounds are reported. These compounds are isomerized to thiol- and dithiolcarbonates by halide ions. Alkylation with alkyl halides gives unstable intermediates which rearrange to β-haloethyl thiol- and dithiolcarbonates. Acids induce polymerization to polythiol and polydithiolcarbonates. Both 1 and 2 give ethylene when treated with triphenylphosphine. Nmr and ir spectral comparisons of the six possible ethylene carbonates with sulfur substituted for oxygen are tabulated. © 1969, American Chemical Society. All rights reserved.

引用

页码：3011 / &

共 28 条

[21] A NEW METHOD FOR THE PREPARATION OF ETHYLENE SULFIDE
REYNOLDS, DD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (18) : 4951 - 4952
[22] SCHOBERL A, 1955, ANN, V595, P101
[23] Schoenberg A., 1930, CHEM BER, V63, P178
[24] SCHONBERG A, 1930, LIEBIGS ANN CHEM, V483, P107
[25] STAAB HA, 1962, LIEBIGS ANN CHEM, V657, P98
[26] TULEEN DS, 1967, J OEG CHEM, V32, P465
[27] WINTER REA, 1964, THESIS HARVARD U, P64
[28] NEIGHBORING GROUP REACTIONS .5. AN UNUSUAL ASSISTED METHANOLYSIS
ZAUGG, HE
MICHAELS, RJ
[J]. TETRAHEDRON, 1962, 18 (AUG) : 893 - &

← 1 2 3 →