ADSORPTION OF DIPOLAR HARD-SPHERES ONTO A SMOOTH, HARD WALL IN THE PRESENCE OF AN ELECTRIC-FIELD

被引:29
作者
ISBISTER, DJ
FREASIER, BC
机构
[1] Department of Chemistry, University of New South Wales, Royal Military College, Duntroon
关键词
adsorption; applied field; Baxter's method; dipolar fluid; Mean spherical approximation; surface phenomena;
D O I
10.1007/BF01011941
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Integral equations have been solved for the density profile of dipolar hard spheres against a hard, smooth wall in the presence of an electric field. This density profile was examined as a function of the bulk medium's temperature and density with different field strengths and field directions. It was found to depend primarily upon the competitive interactions of the field with the monolayer particles and the first outer shell with the monolayer particles. © 1979 Plenum Publishing Corporation.
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页码:331 / 345
页数:15
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