PENDANT-FUNCTIONALIZED LIGANDS FOR METALLOSUPRAMOLECULAR ASSEMBLIES - RUTHENIUM(II) AND OSMIUM(II) COMPLEXES OF 4'-(4-PYRIDYL)-2,2'/6',2''-TERPYRIDINE

被引：135

作者：

CONSTABLE, EC ^{[1
]}

THOMPSON, AMWC ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CAMBRIDGE CTR MOLEC RECOGNIT,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 09期

关键词：

D O I：

10.1039/dt9940001409

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The potentially tetradentate ligand 4'-(4-pyridyl)-2,2':6',2''-terpyridine (pyterpy) acts as a tridentate donor to iron(II), ruthenium(II) and osmium(II). The non-co-ordinated pyridyl group reacts with a range of electrophiles to give complexes containing the cationic ligands Hpyterpy and 4'-(4-methylpyridinio)-2,2':6',2'-terpyridine (mpyterpy). The electrochemical behaviour of these complexes has been studied and correlations between the redox potentials and Hammett sigma+ parameters made.

引用

页码：1409 / 1418

页数：10

共 18 条

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