NOVEL SYNTHESIS OF A DOUBLY CYCLOMETALATED DIRUTHENIUM COMPLEX WITH STRONGLY COUPLED METAL CENTERS

被引：50

作者：

CONSTABLE, EC ^{[1
]}

THOMPSON, AMWC ^{[1
]}

GREULICH, S ^{[1
]}

机构：

[1] ECOLE EUROPEENNE HAUTES ETUDES IND CHIM STRASBOURG EHICS,F-67008 STRASBOURG,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 18期

关键词：

D O I：

10.1039/c39930001444

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel coupling method by which a ruthenium(II) complex of a 4'-chloro-substituted 2,2' : 6',2''-terpyridine is converted to a dinuclear doubly cyclometallated complex is reported; the dinuclear complex can be oxidized to give a strongly coupled mixed-oxidation state Ru(III)Ru(II) species.

引用

页码：1444 / 1446

页数：3

共 22 条

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[3] SYNTHESIS OF BIS-CYCLOMETALLATING N-C-N HEXADENTATE LIGANDS VIA C-C AROMATIC COUPLINGS AND THEIR DINUCLEAR RUTHENIUM(II) COMPLEXES
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[4] LONG-RANGE COUPLING IN A MIXED-VALENCE DIRUTHENIUM COMPLEXES CONTAINING BIS-TERPYRIDINE LIGANDS OF VARIOUS LENGTHS AS BRIDGES
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[5] A ROOM-TEMPERATURE LUMINESCENT CYCLOMETALLATED RUTHENIUM(II) COMPLEX OF 6-PHENYL-2,2'-BIPYRIDINE
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[6] MULTINUCLEATING 2,2'/6',2''-TERPYRIDINE LIGANDS AS BUILDING-BLOCKS FOR THE ASSEMBLY OF COORDINATION POLYMERS AND OLIGOMERS
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[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (24): : 3467 - 3475
[7] SYNTHESIS AND COORDINATION BEHAVIOR OF 6',6''-BIS(2-PYRIDYL)-2,2'-4,4''-2'',2'''-QUATERPYRIDINE - BACK-TO-BACK 2,2'-6',2''-TERPYRIDINE
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[8] A NEW LIGAND FOR THE SELF ASSEMBLY OF STARBURST COORDINATION OLIGOMERS AND POLYMERS
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[9] CONSTABLE EC, 1992, NEW J CHEM, V16, P855
[10] CONSTABLE EC, 1992, SUPRAMOLECULAR CHEM, P319

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