A THEORY OF ELECTRON-TRANSFER AT SUPERCONDUCTING ELECTRODES

被引:22
作者
KUZNETSOV, AM
机构
[1] AN FRUMKIN ELECTROCHEM INST, MOSCOW 117071, USSR
[2] PURDUE UNIV, DEPT CHEM, W LAFAYETTE, IN 47907 USA
关键词
D O I
10.1016/0022-0728(90)85119-P
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A theory of the elementary act of electrochemical electron-transfer reactions at superconducting electrodes is suggested. It is shown that the transition from normal to superconducting state suppresses the one-electron current. The possibility of the appearance of a two-electron current due to the tunnelling of superfluid electron pairs is considered. The effect of a magnetic field on this current is discussed. Short-time measurements using fast pulse heating of the electrolyte by a laser beam are proposed. © 1990.
引用
收藏
页码:1 / 15
页数:15
相关论文
共 24 条
[21]   BULK SUPERCONDUCTIVITY AT 120-K IN THE TL-CA BA-CU-O SYSTEM [J].
SHENG, ZZ ;
HERMANN, AM .
NATURE, 1988, 332 (6160) :138-139
[22]  
ULSTRUP J, 1979, LECTURE NOTES CHEM, V10
[23]  
VOROTYNTSEV MA, 1970, ELEKTROKHIMIYA, V6, P208
[24]  
[No title captured]