5-COORDINATE HYDRIDO OLEFIN PLATINUM(II) COMPLEXES

被引：10

作者：

DEFELICE, V

FERRARA, ML

PANUNZI, A

RUFFO, F

机构：

[1] NAPLES UNIV,DIPARTIMENTO CHIM,VIA MEZZOCANNONE 4,I-80134 NAPLES,ITALY

[2] UNIV MOLISE,FAC AGR,I-86100 CAMPOBASSO,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 439卷 / 02期

关键词：

D O I：

10.1016/0022-328X(92)80238-S

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Stable five-coordinate hydrido/olefin complexes of general formula [Pt(2,9-Me2-1,10-phenanthroline)H(Cl)(olefin)] have been synthesized in high yield through oxidative addition of HCl to [Pt(2,9-Me2-1,10-phenanthroline)(olefin)] precursors. Relevant spectroscopic features and some preliminary results concerning the reactivity of the new compounds are also reported.

引用

页码：C49 / C51

页数：3

共 15 条

[1] SYNTHESIS AND CHARACTERIZATION OF 5-COORDINATE PLATINUM(II) COMPLEXES [PT(2,9-DIMETHYL-1,10-PHENANTHROLINE) (SNRNX3-N)X(OLEFIN)] (X = CL OR BR - R = PH OR ME) - MOLECULAR-STRUCTURE OF [PT(2,9-DIMETHYL-1,10-PHENANTHROLINE)(SNPH2CL)CL(ETHYLENE)]
ALBANO, VG
CASTELLARI, C
DEFELICE, V
PANUNZI, A
RUFFO, F
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 425 (1-2) : 177 - 188
[2] NEIGHBORING GROUP PARTICIPATION OF HALO AND ARYL GROUPS IN THE STOICHIOMETRIC AND CATALYTIC REACTIONS OF OLEFINS WITH TRANSITION-METAL HYDRIDES AND A NEW ROUTE TO ARENE COMPLEXES
CRABTREE, RH
MELLEA, MF
QUIRK, JM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (10) : 2913 - 2917
[3] 5-COORDINATE PLATINUM(2) COMPLEXES
CRAMER, RD
LINDSEY, RV
PREWITT, CT
STOLBERG, UG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (03) : 658 - &
[4] MONOHYDRIDO-BRIDGED PLATINUM(II)-GOLD(I) COMPLEXES - X-RAY CRYSTAL-STRUCTURE OF [(PH3P)2(C6CL5)PT(MU-H)AU(PPH3)]CLO4.2ET2O
CRESPO, M
SALES, J
SOLANS, X
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (06): : 1089 - 1092
[5] 5-COORDINATE OLEFIN COMPLEXES OF PLATINUM(II) CONTAINING SIGMA-BONDED CARBON LIGANDS - COORDINATION ENVIRONMENT AND STABILITY
CUCCIOLITO, ME
DEFELICE, V
PANUNZI, A
VITAGLIANO, A
[J]. ORGANOMETALLICS, 1989, 8 (05) : 1180 - 1187
[6] STABLE 5-COORDINATE [PT(NN')(OLEFIN)(R)X] COMPLEXES FORMED BY OXIDATIVE ADDITION TO [PT(NN')(OLEFIN)] PRECURSORS
DEFELICE, V
FUNICELLO, M
PANUNZI, A
RUFFO, F
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 403 (1-2) : 243 - 252
[7] MECHANISMS OF LIGAND ASSOCIATION IN COMPLEXES OF TYPE RML3+X-(M = NI, PD, PT) .2. MECHANISMS OF REACTIONS HML3+ + L REVERSIBLE HML4+ (L = P(C2H5)3)
ENGLISH, AD
MEAKIN, P
JESSON, JP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (02) : 422 - 436
[8] SYNTHESIS AND NMR-SPECTROSCOPY OF 5-COORDINATE PLATINUM(II) HYDRIDE COMPLEXES
HANDLER, A
PERINGER, P
MULLER, EP
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 412 (03) : 451 - 456
[9] HECK RF, 1982, ORG REACTIONS, V27, P345
[10] HYDRIDE COMPLEXES OF TRANSITION-METALS
KAESZ, HD
SAILLANT, RB
[J]. CHEMICAL REVIEWS, 1972, 72 (03) : 231 - &

← 1 2 →