CROSS-LINKING OF STYRENE-BUTADIENE RUBBER WITH POLYURETHANES BICAPPED WITH BENZYOCYCLOBUTENE

被引：10

作者：

DEEKEN, JS ^{[1
]}

FARONA, MF ^{[1
]}

机构：

[1] UNIV N CAROLINA, DEPT CHEM, GREENSBORO, NC 27412 USA

来源：

POLYMER BULLETIN | 1992年 / 29卷 / 3-4期

关键词：

D O I：

10.1007/BF00944822

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A polyurethane prepared from 1,9-nonanediol and toluene-2,4-diisocyanate with M(n)=11,840, was capped on both ends in a reaction with 4-(benzocyclobutenyl)methanol. The polyurethane was used to crosslink styrene-butadiene rubber through Diels-Alder reactions on the benzocyclobutene functionality. The synthesis and characterization of 4-(benzocyclobutenyl)methanol, a molecule not reported previously, is presented. The crosslinking reaction was carried out on intimate mixtures of the telechelic polyurethane and SBR at elevated temperature and pressure. Various physical properties of the crosslinked material were studied.

引用

页码：295 / 301

页数：7

共 15 条

[1] COPOLYMERS OF SUBSTITUTED ACETYLENES AND ETHYNYLBENZOCYCLOBUTENES [J].