BETA-PHOSPHORYLATED 5 MEMBERED RING NITROXIDES - SYNTHESIS AND EPR STUDY

被引:29
作者
DEMBKOWSKI, L [1 ]
FINET, JP [1 ]
FREJAVILLE, C [1 ]
LEMOIGNE, F [1 ]
MAURIN, R [1 ]
MERCIER, A [1 ]
PAGES, P [1 ]
STIPA, P [1 ]
TORDO, P [1 ]
机构
[1] UNIV AIX MARSEILLE 1,CNRS,URA 1412,RADICAUX LIBRES & SYNTHESE,CASE 521,F-13397 MARSEILLE 4,FRANCE
来源
FREE RADICAL RESEARCH COMMUNICATIONS | 1993年 / 19卷
关键词
BETA-PHOSPHORYLATED NITROXIDES; ALPHA-AMINOPHOSPHONATES; INTRAMOLECULAR AMINOMERCURATION; 1-PYRROLINE-N-OXIDES; EPR;
D O I
10.3109/10715769309056s23
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
A series of stable beta-phosphorylated five membered ring nitroxides was prepared by intramolecular aminomercuration of alkenyl alpha-aminophosphonates. The structure of these nitroxides was deduced from their C-13 and P-31 coupling constants and from force field calculations.
引用
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页码:S23 / S32
页数:10
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