EQUILIBRIUM BETWEEN ISOCYANIDE AND CARBENE COMPLEXES IN COORDINATION-COMPOUNDS OF 2,6-DIHYDROXYPHENYL ISOCYANIDE

被引：65

作者：

HAHN, FE

TAMM, M

LUGGER, T

机构：

[1] Institut Für Anorganische Und Analytische Chemie, Freien Universität, Berlin, D-14195

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 13期

关键词：

D O I：

10.1002/anie.199413561

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The selective shift of the equilibrium in the title (1⇌2) is achieved by reaction with bases: weak bases such as NEt3 or DABCO yield isocyanide complexes like 3; strong bases such as KOtBu (+ MeI) afford carbene complexes like 4. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1356 / 1359

页数：4

共 8 条

[1] VIBRATIONAL SPECTRA AND BONDING IN METAL CARBONYLS .1. INFRARED SPECTRA OF PHOSPHINE-SUBSTITUTED GROUP VI CARBONYLS IN CO STRETCHING REGION [J].