On the reversibility of hydroxyphosphonate formation in the Kabachnik-Fields reaction

被引：43

作者：

Gancarz, R ^{[1
]}

Gancarz, I ^{[1
]}

Walkowiak, U ^{[1
]}

机构：

[1] WROCLAW TECH UNIV,INST ORGAN TECHNOL & PLAST,PL-50370 WROCLAW,POLAND

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1995年 / 104卷 / 1-4期

关键词：

Kabachnik-Fields synthesis; hydroxyphosphonate; aminophosphonate;

D O I：

10.1080/10426509508042576

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reversibility of hydroxyphosphonate synthesis in the Kabachnik-Fields synthesis was studied. It was found that in all studies cases which included aliphatic and aromatic aldehydes or ketones the hydroxyphosphonates decompose to the starting ketone and dialkyl phosphite in the presence of aliphatic amines as determined by H-1-, C-13-, P-31-NMR.

引用

页码：45 / 52

页数：8