SYNTHESIS OF N-METHYLIMINOSULFUR TETRAFLUORIDE, CH3N=SF4, FROM CATION CH3NSF+3

被引：36

作者：

MEWS, R

机构：

[1] Anorganisch-Chemisches Institut Der Universität, Göttingen, D-3400

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1978年 / 17卷 / 07期

关键词：

D O I：

10.1002/anie.197805301

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stepwise addition of polar reagents Rδ+ Fδ− to NSF3 1 was formerly impossible in the case of “methyl fluoride”; the salt (2) and the tetrafluoride (3) are stable compounds. (Formula Presented.) Copyright © 1978 by Verlag Chemie, GmbH, Germany

引用

页码：530 / 530

页数：1

共 11 条

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[6] MEWS R, UNPUBLISHED
[7] MEWS R, 1976, ADV INORG CHEM, V19, P185
[8] 5-COORDINATE STEREOCHEMISTRY
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[9] IR-SPEKTRUM UND STRUKTUR DER VERBINDUNG NSF3 . BF3
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[10] FRIEDEL-CRAFTS CHEMISTRY .10. OBSERVATION OF METHYL FLUORIDE-ANTIMONY PENTAFLUORIDE COMPLEX IN SULFURYL FLUORIDE SOLUTION, AN EXCEEDINGLY LOW NUCLEOPHILICITY SOLVENT - REINVESTIGATION OF COMPLEX IN SULFUR-DIOXIDE AND SULFURYL CHLORIDE FLUORIDE SOLUTION SHOWING O-METHYLATION
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LIN, HC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (09) : 2661 - 2663

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