SYNTHESIS OF CATIONIC ETA(2)-PHOSPHINOCARBENE COMPLEXES OF MOLYBDENUM AND TUNGSTEN

被引：16

作者：

KREISSL, FR

OSTERMEIER, J

OGRIC, C

机构：

[1] Anoanorganisch-Chemisches Institut, Technischen Universität München, Garching, D-85747

来源：

CHEMISCHE BERICHTE | 1995年 / 128卷 / 03期

关键词：

ETA(2)-PHOSPHINOCARBENE COMPLEXES OF MOLYBDENUM AND TUNGSTEN; CARBYNE COMPLEXES; CHLORDIMETHYLPHOSPHANE; CHLORDIPHENYLPHOSPHANE; ELECTROPHILIC ADDITION;

D O I：

10.1002/cber.19951280313

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of chlordimethylphosphane or chlordiphenylphosphane and sodium tetraphenylborate with dicarbonyl(eta(5)-cyclopentadienyl)carbyne complexes of molybdenum and tungsten enables the direct conversion of a M=CR group into a M=C(R)-PR(2) unit providing dicarbonyl substituted eta(2)-phosphinocarbene complexes in high yields. In the absence of Na[BPh(4)] a base induced carbonyl carbene coupling reaction affords eta(3)-phosphinoketene complexes.

引用

页码：289 / 292

页数：4

共 68 条

[31] HUY NHT, 1988, ORGANOMETALLICS, V7, P240
[32] Karsch H. H., 1975, ANGEW CHEM, V87, P630
[33] KARSCH HH, 1989, NEW J CHEM, V13, P319
[34] FUNCTIONAL DERIVATIVES OF TRIMETHYLPHOSPHINE .2. AMBIVALENT BEHAVIOR OF TETRAKIS(TRIMETHYLPHOSPHINE)IRON - EQUILIBRIUM OF ISOMERS
KARSCH, HH
KLEIN, HF
SCHMIDBAUR, H
[J]. CHEMISCHE BERICHTE-RECUEIL, 1977, 110 (06): : 2200 - 2212
[35] FUNCTIONAL DERIVATIVES OF TRIMETHYLPHOSPHINE .6. "LITHIUM-DIMETHYLPHOSPHINOMETHANIDE, (CH3)2PCH2LI, TETRAORGANODIPHOSPHINOMETHANES, R2PCH2P(CH3)2, AND TRIS(DIMETHYLPHOSPHINOMETHYL)PHOSPHINE, P[CH2P(CH3)2]3
KARSCH, HH
SCHMIDBAUR, H
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1977, 32 (07): : 762 - 767
[36] COMPLEXES WITH ALKYL SUBSTITUTED PHOSPHINOMETHANES AND PHOSPHINOMETHANIDES .7. MONOPHOSPHINOMETHANIDES AND DIPHOSPHINOMETHANIDES AS CHELATE LIGANDS IN IRON-COMPLEXES, COBALT-COMPLEXES, AND NICKEL-COMPLEXES
KARSCH, HH
[J]. CHEMISCHE BERICHTE-RECUEIL, 1984, 117 (02): : 783 - 796
[37] ZIRCONIUM COMPLEXES WITH PHOSPHINOMETHANIDE LIGANDS - SYNTHESES, REACTIVITY, AND X-RAY STRUCTURE DETERMINATIONS
KARSCH, HH
GRAUVOGL, G
KAWECKI, M
BISSINGER, P
KUMBERGER, O
SCHIER, A
MULLER, G
[J]. ORGANOMETALLICS, 1994, 13 (02) : 610 - 618
[38] DIMETHYLPHOSPHINOMETHANIDE ION, (CH3)2PCH2- - NOVEL LIGAND FOR TRANSITION-METALS
KARSCH, HH
KLEIN, HF
SCHMIDBAUR, H
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1975, 14 (09): : 637 - 638
[39] REACTIONS OF THE THIOCARBENE COMPLEX [HB(PZ)3](CO)2W[ETA-2-CH(SME)]+ WITH SULFUR, CARBON, AND NITROGEN NUCLEOPHILES
KIM, HP
ANGELICI, RJ
[J]. ORGANOMETALLICS, 1986, 5 (12) : 2489 - 2496
[40] REACTIONS OF THE THIOCARBYNE [HB(PZ)3](CO)2W(=CSME) AND THIOCARBENE [HB(PZ)3](CO)2W[ETA-2-CH(SME)]+ COMPLEXES WITH PHOSPHINES
KIM, HP
KIM, S
JACOBSON, RA
ANGELICI, RJ
[J]. ORGANOMETALLICS, 1986, 5 (12) : 2481 - 2488

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