[V(SNC9H6)3] AND [V(SNH2C6H4)2(SNHC6H4)]-, HOMOLEPTIC VANADIUM(III) COMPLEXES WITH SULFUR NITROGEN DONOR LIGANDS, AND [V(SNC5H4)3]-, THE 1ST THIOLATOVANADIUM(II) COMPLEX

被引：16

作者：

HENKEL, G ^{[1
]}

KREBS, B ^{[1
]}

SCHMIDT, W ^{[1
]}

机构：

[1] UNIV MUNSTER, INST ANORGAN CHEM, W-4400 MUNSTER, GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1992年 / 31卷 / 10期

关键词：

D O I：

10.1002/anie.199213661

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The sulfur and nitrogen atoms of the pyridinethiolato ligands coordinate to the central atom in the vanadium(II) complex [V(SNC5H4)3]- (1) to form a distorted octahedral geometry. In each set of neighboring ligands one S atom and one N atom are trans to each other; the chelate rings are planar. Such complexes with bifunctional ligands are important as models for vanadium centers in biomolecules.

引用

页码：1366 / 1368

页数：3

共 12 条

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