DETERMINATION OF HENRY LAW CONSTANTS OF ORGANICS IN DILUTE AQUEOUS-SOLUTIONS

被引：44

作者：

HANSEN, KC ^{[1
]}

ZHOU, Z ^{[1
]}

YAWS, CL ^{[1
]}

AMINABHAVI, TM ^{[1
]}

机构：

[1] LAMAR UNIV,DEPT CHEM ENGN,BEAUMONT,TX 77710

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1993年 / 38卷 / 04期

关键词：

D O I：

10.1021/je00012a017

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Henry's law constants of 15 volatile organic compounds in dilute aqueous solutions were measured by the procedure of equilibrium partitioning in a closed system. The method is based upon the measurement of the headspace concentration by gas chromatography. The compounds investigated included six halogenated hydrocarbons, four aromatic hydrocarbons, and five alkanes. The measurements were made at three temperatures between 25 and 45-degrees-C. The measured Henry's law constants compared well with the literature data of some liquids. The temperature dependence of Henry's law constant was also studied from the van't Hoff relation.

引用

页码：546 / 550

页数：5