LIGAND-EXCHANGE IN ADDUCTS OF ETHYLALUMINUM HYDRIDES

被引：3

作者：

FRIGO, DM

REUVERS, PJ

BRADLEY, DC

CHUDZYNSKA, H

MEINEMA, HA

KRAAIJKAMP, JG

TIMMER, K

机构：

[1] QUEEN MARY & WESTFIELD COLL,LONDON E1 4NS,ENGLAND

[2] TNO,DEPT CHEM,3700 AC ZEIST,NETHERLANDS

来源：

CHEMISTRY OF MATERIALS | 1991年 / 3卷 / 06期

关键词：

D O I：

10.1021/cm00018a028

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The compounds EtAlH2.NMe3 and Et2AlH.NMe3 have been shown by H-1 NMR spectroscopy to be fluxional mixtures of all species EtxAlH3-x.NMe3 (x = 0-3) in aromatic solvents. The pure liquids have also been shown to be mixtures by their volatilization behavior, and the tendency for EtAlH2.NMe3 to separate at low temperatures into a solid plus a liquid, each of which has a different composition. This has potentially dire consequences for the usefulness of both of these compounds as precursors for the MOCVD of aluminum-containing layers.

引用

页码：1097 / 1101

页数：5

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