DETECTION OF CYCLOHEXYL HYDROPEROXIDE AS AN INTERMEDIATE IN GIF TYPE OXIDATION OF CYCLOHEXANE TO CYCLOHEXANONE USING C-13 NMR-SPECTROSCOPY

被引：45

作者：

BARTON, DHR ^{[1
]}

CSUHAI, E ^{[1
]}

DOLLER, D ^{[1
]}

BALAVOINE, G ^{[1
]}

机构：

[1] UNIV PARIS 11,INST CHIM MOLEC,CNRS,LAB 225,F-91405 ORSAY,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1990年 / 24期

关键词：

D O I：

10.1039/c39900001787

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The oxidation of [1-C-13]cyclohexane to cyclohexanone under GoAgg(II) conditions is followed using C-13 NMR spectroscopy; cyclohexyl hydroperoxide is an intermediate which is transformed quantitatively into cyclohexanone.

引用

页码：1787 / 1789

页数：3

共 14 条

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