A STUDY OF THE INTRAMOLECULAR STILLE CROSS-COUPLING REACTION OF VINYLSTANNYL CHLOROFORMATES - APPLICATION TO THE SYNTHESIS OF ALPHA-METHYLENE LACTONES

被引：11

作者：

ADLINGTON, RM

BALDWIN, JE

GANSAUER, A

MCCOULL, W

RUSSELL, AT

机构：

[1] Dyson Perrins Laboratory, University of Oxford, Oxford OX1 3QY, South Parks Road

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1994年 / 13期

关键词：

D O I：

10.1039/p19940001697

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An intramolecular Stille cross coupling of vinylstannyl chloroformates catalysed by trans-benzylchlorobis(triphenylphosphine) palladium(II) has been investigated and shown to be useful for the preparation of alpha-methylene lactones. A novel method for the chloroformylation of alcohols in the presence of vinylstannanes is also described.

引用

收藏

页码：1697 / 1701

页数：5

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