RUTHENIUM-CATALYZED OXIDATION OF TERTIARY-AMINES WITH HYDROGEN-PEROXIDE IN THE PRESENCE OF METHANOL

被引：88

作者：

MURAHASHI, SI

NAOTA, T

MIYAGUCHI, N

NAKATO, T

机构：

[1] Department of Chemistry, Faculty of Engineering Science, Osaka University Machikaneyama, Toyonaka, Osaka

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 46期

关键词：

D O I：

10.1016/S0040-4039(00)60914-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alpha-Methoxylation of tertiary amines can be performed by the ruthenium-catalyzed oxidation of tertiary amines with hydrogen peroxide in the presence of methanol. The reaction provides an efficient method for selective N-demethylation of tertiary methylamines and construction of quinoline skeletons.

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页码：6991 / 6994

页数：4

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