OPTICALLY-ACTIVE DIAZACYCLOPHOSPHAMIDES - NOVEL EFFICIENT REAGENTS FOR THE DETERMINATION OF THE ABSOLUTE-CONFIGURATION OF AMINES AND ALCOHOLS

被引：20

作者：

OSHIKAWA, T

YAMASHITA, M

KUMAGAI, S

SEO, K

KOBAYASHI, J

机构：

[1] NUMAZU TECH COLL,DEPT MAT SCI,NUMAZU 410,JAPAN

[2] SHIZUOKA INST SCI & TECHNOL,DEPT MAT SCI,FUKUROI 437,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 04期

关键词：

D O I：

10.1039/c39950000435

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Various amines and alcohols are converted into the corresponding phosphamides by the action of optically active diazacyclophosphamidic chlorides and absolute configurations of amines and alcohols are readily determined by proton and phosphorus NMR of the cyclophosphamides that are formed.

引用

收藏

页码：435 / 436

页数：2

相关论文

共 15 条

[1] A NEW REAGENT FOR A VERY SIMPLE AND EFFICIENT DETERMINATION OF ENANTIOMERIC PURITY OF ALCOHOLS BY P-31 NMR [J].

ALEXAKIS, A ;

MUTTI, S ;

NORMANT, JF ;

MANGENEY, P .

TETRAHEDRON-ASYMMETRY, 1990, 1 (07) :437-440

[2]

COOPER DB, 1974, TETRAHEDRON LETT, P2697

[3] 1,3,2-OXAZAPHOSPHOLIDINES FROM (-)-EPHEDRINE - INTERMEDIATES FOR STEREOSPECIFIC SYNTHESIS OF OPTICALLY-ACTIVE DIALKYL ALKYLPHOSPHONOTHIOATES AND DIALKYL ALKYLPHOSPHONO-SELENOATES, TRIALKYL PHOSPHORO-THIOATES AND TRIALKYL PHOSPHONO-SELENOATES, DIALKYL METHYLPHOSPHONATES, AND TRIALKYL PHOSPHATES [J].

COOPER, DB ;

HALL, CR ;

HARRISON, JM ;

INCH, TD .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1977, (17) :1969-1980

[4] NUCLEAR MAGNETIC-RESONANCE ENANTIOMER REAGENTS - CONFIGURATIONAL CORRELATIONS VIA NUCLEAR MAGNETIC-RESONANCE CHEMICAL-SHIFTS OF DIASTEREOMERIC MANDELATE, O-METHYLMANDELATE, AND ALPHA-METHOXY-ALPHA-TRIFLUOROMETHYLPHENYLACETATE (MTPA) ESTERS [J].

DALE, JA ;

MOSHER, HS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (02) :512-519

[5] PHOSPHORUS CONTAINING HETEROCYCLES .23. PMR STUDY OF OXAZAPHOSPHOLANE-1,3,2 DERIVATIVES .3. INTERPRETATION OF RESULTS - TENTATIVE CONFORMATIONAL-ANALYSIS [J].

DEVILLER.J ;

CORNUS, M ;

NAVECH, J .

ORGANIC MAGNETIC RESONANCE, 1974, 6 (04) :211-220

[6] SIMPLE P-31 NMR METHOD FOR THE DETERMINATION OF ENANTIOMERIC PURITY OF ALCOHOLS NOT REQUIRING CHIRAL AUXILIARY COMPOUNDS [J].

FERINGA, BL ;

SMAARDIJK, A ;

WYNBERG, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (16) :4798-4799

[7]

HULLST R, 1993, TETRAHEDRON LETT, P1339

[8]

HULST R, 1992, ANGEW CHEM INT EDIT, V31, P1092, DOI 10.1002/anie.199210921

[9] CALCULATION OF NUCLEAR MAGNETIC RESONANCE SPECTRA OF AROMATIC HYDROCARBONS [J].

JOHNSON, CE ;

BOVEY, FA .

JOURNAL OF CHEMICAL PHYSICS, 1958, 29 (05) :1012-1014

[10] DETERMINATION OF ENANTIOMERIC PURITIES OF ALCOHOLS AND AMINES BY A P-31 NMR TECHNIQUE [J].

JOHNSON, CR ;

ELLIOTT, RC ;

PENNING, TD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (17) :5019-5020